Settore ERC

PE5_9 - Environment chemistry
PE5_10 - Coordination chemistry
PE5_17 - Supramolecular chemistry

Attività

Design and synthesis of ligands suitable for the coordination of 3d and 4f transition metals.

Investigation of methods for the separation of mixtures of metals of the d and f transition series.

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Structural characterizati
on of organic and organometallic compounds by single crystal X-ray diffraction.
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Equipment

Laboratorio di Chimica Inorganica (13.01.1.056)

Laboratorio XRD cristallo singolo / materiali policristallini (13.01.S.035)


Projects

  • GREEn SM - Green processes for Rare Earth Elements Separation, recovery & valorization from permanent Magnets. PRIN 2023-2025.

Prodotti della ricerca

Publications

Mara, Cai, Bonabello, Penna, Van Deun, Deplano, Marchiò, Pilia, Artizzu.
Spectral Tuning and Emission Enhancement through Lanthanide Coordination in a Dual Visible-Near-Infrared Emissive Cyanide-Bridged Heterometallic Ru(II)-Er(III) Complex.
(2024) Crystal Growth and Design, 24 (9), pp. 3798-3808.
DOI: 10.1021/acs.cgd.4c00115

Baraldi, Bassanetti, Amadei, Bacchi, Marchiò.
Salts and Cocrystals of Benzocaine with Increased Dissolution Rate and Permeability Open New Avenues for Enhancing the Duration of Action.
(2024) Crystal Growth and Design, 24 (5), pp. 2157-2167.
DOI: 10.1021/acs.cgd.3c01488

Perego, Daolio, Bezuidenhout, Piva, Prando, Costarella, Carretta, Marchiò, Kubicki, Sozzani, Bracco, Comotti.
Solid State Machinery of Multiple Dynamic Elements in a Metal–Organic Framework.
(2024) Angewandte Chemie – Int. Ed., 63, e202317094.
DOI: 10.1002/anie.202317094

Melegari, Neri, Falco, Tegoni, Maffini, Fornari, Mucchino, Artizzu, Serpe, Marchiò.
Tailoring the Use of 8-Hydroxyquinolines for the Facile Separation of Iron, Dysprosium and Neodymium.
(2024) ChemSusChem.
DOI: 10.1002/cssc.202400286

Melegari, Marzaroli, Polisicchio, Seletti, Marchiò, Pecoraro, Tegoni.
Insights on the Structure in Solution of Paramagnetic LnIII/GaIII 12-Metallacrown-4 Complexes Using 1D 1H NMR and Model Structures.
(2023) Inorganic Chemistry, 62, 10645-10654.
DOI: 10.1021/acs.inorgchem.3c00983

Artizzu, Pilia, Serpe, Mara, Casula, Marchiò, Deplano.
Anion-Induced Structural Diversity and Optical Chromism in a Series of Cyano-Bridged Heterometallic 3d-4f Coordination Polymers.
(2023) Molecules.
DOI: 10.3390/molecules28062871

Falco, Neri, Melegari, Baraldi, Bonfant, Tegoni, Serpe, Marchiò.
Semirigid Ligands Enhance Different Coordination Behavior of Nd and Dy Relevant to Their Separation and Recovery in a Non-aqueous Environment.
(2022) Inorganic Chemistry, 61, 16110-16121.
DOI: 10.1021/acs.inorgchem.2c02619

Bonfant, Balestri, Perego, Comotti, Bracco, Koepf, Gennari, Marchiò.
Phosphine Oxide Porous Organic Polymers Incorporating Cobalt(II) Ions: Synthesis, Characterization, and Investigation of H2 Production.
(2022) ACS Omega, 7, 6104-6112.
DOI: 10.1021/acsomega.1c06522

Baraldi, Fornasari, Bassanetti, Amadei, Bacchi, Marchiò.
Salification Controls the In-Vitro Release of Theophylline.
(2022) Crystals.
DOI: 10.3390/cryst12020201

Perego, Bezuidenhout, Bracco, Prando, Marchiò, Negroni, Carretta, Sozzani, Comotti.
Cascade Dynamics of Multiple Molecular Rotors in a MOF: Benchmark Mobility at a Few Kelvins and Dynamics Control by CO2.
(2021) Journal of the American Chemical Society, 143, 13082-13090.
DOI: 10.1021/jacs.1c03801

Gullo, Baldini, Casnati, Marchiò.
Halogen Bonds Direct the Solid State Architectures of a Multivalent Iodopropargylcalix[4]arene.
(2020) Crystal Growth and Design, 20, 3611-3616.
DOI: 10.1021/acs.cgd.0c00442

Bonfant, Melegari, Balestri, Mezzadri, Marzaroli, Bassanetti, Marchiò.
Supramolecular Assemblies in Silver Complexes: Phase Transitions and the Role of the Halogen Bond.
(2020) Inorganic Chemistry, 59, 4140-4149.
DOI: 10.1021/acs.inorgchem.0c00256

Jantan, Chan, Melis, White, Marchiò, Deplano, Serpe, Wilton-Ely.
From recovered palladium to molecular and nanoscale catalysts.
(2019) ACS Sustainable Chemistry and Engineering, 7, 12389-12398.
DOI: 10.1021/acssuschemeng.9b01877

Marzaroli, Spigolon, Lococciolo, Quaretti, Salviati, Kampf, Licini, Marchiò, Pecoraro, Tegoni.
Three-Dimensional Porous Architectures Based on Mn II/III Three-Blade Paddle Wheel Metallacryptates.
(2019) Crystal Growth and Design, 19, 1954-1964.
DOI: 10.1021/acs.cgd.8b01921



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