Crystal Engineering
- Unità di Chimica Analitica, dei Beni Culturali, Inorganica e Cristallografia
Componenti
- Bacchi Prof.ssa Alessia (Coordinatore)
- Pelagatti Prof. Paolo (Coordinatore)
- Mazzeo Prof. Paolo Pio (Coordinatore)
- Prencipe Michele (Dottorando)
- Giovanardi Dott. Dario (Dottorando)
- Cicconi Giuditta (Studente)
- Casali Alessandro (Dottorando)
- Piombo Beatrice (Studente)
- Cagossi Giorgio (Dottorando)
- Abodunrin Olabise Temitope (Membro)
- Napolitano Marta (Borsista)
- Martina Orlandini (Membro)
Contatti
Attività
Settore ERC
The group research interests are focused on crystal engineering of polymorphs, solvates, co-crystals, and of responsive organic/inorganic materials. Within this broad theme we developed crystalline molecular and polymeric (MOF) materials capable to reversibly capture and release volatile guestsin a solid/gas and solid/liquid exchange, and proposed structural models to map the process of molecular recognition between the crystalline receptor and the volatile substrate. Recently we focused on the design and control of crystal forms of molecular compounds, and on the stabilization inside crystalline structures (MOF and cocrystals) of liquid and volatile compounds related to human health, environment and nutrition.
Prodotti della ricerca
Bis-isonicotinoyl linkers containing polyaromatic scaffolds: synthesis, structure and spectroscopic properties.
https://air.unipr.it/handle/11381/2910392
Salification Controls the In-Vitro Release of Theophylline.
https://air.unipr.it/handle/11381/2916268
Synthesis, crystal structure, structural phase transition and dielectric properties of new organic-inorganic hybrid compound: (C6H5CH2N(C2H5)3)CdCl3.
https://air.unipr.it/handle/11381/2920249
Development of novel cocrystal-based active food packaging by a quality by design approach.
https://air.unipr.it/handle/11381/2886694
Deciphering the Supramolecular Organization of Multiple Guests Inside a Microporous MOF to Understand their Release Profile.
https://air.unipr.it/handle/11381/2892805
Cocrystallization as a tool to stabilize liquid active ingredients.
https://air.unipr.it/handle/11381/2898533.1
Changing the game of time resolved X-ray diffraction on the mechanochemistry playground by downsizing.
https://air.unipr.it/handle/11381/2902365
Synthesis, characterization, antimicrobial and cytotoxic activity and DNA-binding properties of d-metal complexes with hydrazones of Girard’s T and P reagents.
https://air.unipr.it/handle/11381/2898535
Two crystal forms of a hydrated 2:1 b-cyclodextrin× fluconazole complex: Single crystal x-ray structures, dehydration profiles, and conditions for their individual isolation.
https://air.unipr.it/handle/11381/2899946
Stabilization of liquid active guests via nanoconfinement into a flexible microporous Metal-Organic Framework.
https://air.unipr.it/handle/11381/2912964
On the nature of recurrent Au⋯π motifs in tris(2,2′-bipyridine)M(ii) (M = Fe, Co and Ni) dicyanoaurate(i) salts: X-ray analysis and theoretical rationalization.
https://air.unipr.it/handle/11381/2911095
Mechanochemical Preparation of Dipyridyl-Naphthalenediimide Cocrystals: Relative Role of Halogen-Bond and π-πInteractions.
https://air.unipr.it/handle/11381/2898537
Systematic coformer contribution to cocrystal stabilization: Energy and packing trends.
https://air.unipr.it/handle/11381/2885036
Synthesis, spectroscopic and structural characterization and solution stability of ruthenium sandwich complexes containing 1,8-naphthalimide ligands.
https://air.unipr.it/handle/11381/2886392
Diversity through similarity: a world of polymorphs, solid solutions, cocrystals in a vial of 4,4'-diazopyridine.
https://air.unipr.it/handle/11381/2869911
The chiral 1:2 adduct (S)S(S)C(-)589-ethyl 2-phenylbutyl sulphide-mercury (II) chloride:(-)589[(S)S(S)C-Et(2-PhBu)S.(HgCl2)2]. Stereoselective synthesis, asymmetric oxidation, crystal and molecular structure and circular dichroism spectra.
https://air.unipr.it/handle/11381/2881854
On the entropy cost of making solvates.
https://air.unipr.it/handle/11381/2879273
Site-Selective Double and Tetracyclization Routes to Fused Polyheterocyclic Structures by Pd-Catalyzed Carbonylation Reactions.
https://air.unipr.it/handle/11381/2873751
A zinc mixed-ligand microporous metal-organic framework as solid-phase microextraction coating for priority polycyclic aromatic hydrocarbons from water samples.
https://air.unipr.it/handle/11381/2874281
Crystal engineering guidelines for ruthenium based wheel-and-axle compounds.
https://air.unipr.it/handle/11381/2882708
Crystal structure, vibrational, electrical, optical and DFT study of C2H10N2(IO3)2.HIO3.
https://air.unipr.it/handle/11381/2875508
MOF transmetalation beyond cation substitution: Defective distortion of IRMOF-9 in the spotlight.
https://air.unipr.it/handle/11381/2857851
Structural, thermal and topological characterization of coordination networks containing flexible aminocarboxylate ligands with a central biphenylene scaffold.
https://air.unipr.it/handle/11381/2866307
X-ray, optical, vibrational, electrical, and DFT study of the polymorphic structure of ethylenediammonium bis iodate α-C2H10N2(IO3)2 and β-C2H10N2(IO3)2.
https://air.unipr.it/handle/11381/2858118
Lanthanide coordination polymers based on flexible ligands derived from iminodiacetic acid.
https://air.unipr.it/handle/11381/2866359
Supramolecular assemblies in Pb(II) complexes with hydrazido-based ligands.
https://air.unipr.it/handle/11381/2866362
Stepwise Evolution of Molecular Nanoaggregates Inside the Pores of a Highly Flexible Metal–Organic Framework.
https://air.unipr.it/handle/11381/2866310
Designing a palette of Cocrystals based on Essential Oil constituents for agricultural applications.
https://air.unipr.it/handle/11381/2863639
Structure, vibrational, electrical and optical study of [C2H10N2] (IO3)2·4HIO3.
https://air.unipr.it/handle/11381/2853806
Synthesis of Imidazolidin-2-ones and Imidazol-2-ones via Base-Catalyzed Intramolecular Hydroamidation of Propargylic Ureas under Ambient Conditions.
https://air.unipr.it/handle/11381/2857813
Changing the Dress to a MOF through Fluorination and Transmetalation. Structural and Gas-Sorption Effects.
https://air.unipr.it/handle/11381/2850963
Extension of the Pd-catalyzed CN bond forming reaction to the synthesis of large polydentate ligands containing NH functions.
https://air.unipr.it/handle/11381/2835620
Drinking and Breathing: Solvent Coordination-driven Plasticity of IRMOF-9.
https://air.unipr.it/handle/11381/2858182
The Use of Databases in the Study of Intermolecular Interactions.
https://air.unipr.it/handle/11381/2848821
Linker dependent dimensionality in Zn(II)-coordination polymers containing a flexible bis-pyridyl-bis-amide ligand.
https://air.unipr.it/handle/11381/2850962
Bacchi, Alessia (2018)
The Use of Databases in the Study of Intermolecular Interactions.
https://air.unipr.it/handle/11381/2848821
Balestri, Davide, Bassanetti, Irene, Canossa, Stefano, Gazzurelli, Cristina, Bacchi, Alessia, Bracco, Silvia, Comotti, Angiolina, Pelagatti, Paolo (2018)
Changing the Dress to a MOF through Fluorination and Transmetalation. Structural and Gas-Sorption Effects.
https://air.unipr.it/handle/11381/2850963
Bacchi, Alessia (2018)
Intermolecular Interactions in Crystals.
https://air.unipr.it/handle/11381/2851756
Canossa, Stefano, Bacchi, Alessia, Graiff, Claudia, Pelagatti, Paolo, Predieri, Giovanni, Ienco, Andrea, Manca, Gabriele, Mealli, Carlo (2017)
Hierarchy of Supramolecular Arrangements and Building Blocks: Inverted Paradigm of Crystal Engineering in the Unprecedented Metal Coordination of Methylene Blue.
https://air.unipr.it/handle/11381/2822879
Paolo, Pagano, Pelagatti, Paolo, Bacchi, Alessia, Michele R , Chierotti, Susan A , Bourne, Gift, Mehlana (2017)
SORPTION PROPERTIES TOWARDS ENVIRONMENTALLY IMPORTANT VOCs of HALF-SANDWICH Ru(II) COMPLEXES CONTAINING PERYLENE-BIS-IMIDE LIGANDS.
https://air.unipr.it/handle/11381/2827570
Capucci, Davide, Balestri, Davide, Mazzeo, PAOLO PIO, Pelagatti, Paolo, Rubini, K , Bacchi, Alessia (2017)
Liquid Nicotine Tamed in Solid Forms by Cocrystallization.
https://air.unipr.it/handle/11381/2830678
Mahmoudi, Ghodrat, Gurbanov, Atash V , Rodríguez-Hermida, Sabina, Carballo, Rosa, Amini, Mojtaba, Bacchi, Alessia, Mitoraj, Mariusz P , Sagan, Filip, Kukulka, Mercedes, Safin, Damir A (2017)
Ligand-Driven Coordination Sphere-Induced Engineering of Hybride Materials Constructed from PbCl2 and Bis-Pyridyl Organic Linkers for Single-Component Light-Emitting Phosphors.
https://air.unipr.it/handle/11381/2848811
Alessia Bacchi, *, Davide Capucci, †, Marco Giannetto, †, Monica Mattarozzi, †, Paolo Pelagatti, †, Nair Rodriguez-Hornedo, †, Katia Rubini, ‡, Andrea, Sala (2016)
Turning Liquid Propofol into Solid (without Freezing It): Thermodynamic Characterization of Pharmaceutical Cocrystals Built with a Liquid Drug.
https://air.unipr.it/handle/11381/2817274
Bacchi, Alessia (2016)
Crystallography - A very short introduction.
https://air.unipr.it/handle/11381/2817889
Puentes, Roberto, Torres, Julia, Kremer, Carlos, Cano, Joan, Lloret, Francesc, Capucci, Davide, Bacchi, Alessia (2016)
Mononuclear and polynuclear complexes ligated by an iminodiacetic acid derivative: synthesis, structure, solution studies and magnetic properties.
https://air.unipr.it/handle/11381/2806070
Micheli, Fabrizio, Bacchi, Alessia, Braggio, Simone, Castelletti, Laura, Cavallini, Palmina, Cavanni, Paolo, Cremonesi, Susanna, Dal Cin, Michele, Feriani, Aldo, Gehanne, Sylvie, Kajbaf, Mahmud, Marchio', , Luciano, Nola, Selena, Oliosi, Beatrice, Pellacani, Annalisa, Perdonà, Elisabetta, Sava, Anna, Semeraro, Teresa, Tarsi, Luca, Tomelleri, Silvia, Wong, Andrea, Visentini, Filippo, Zonzini, Laura, Heidbreder, Christian (2016)
1,2,4-Triazolyl 5-Azaspiro[2.4]heptanes: Lead Identification and Early Lead Optimization of a New Series of Potent and Selective Dopamine D3 Receptor Antagonists.
https://air.unipr.it/handle/11381/2817890
Bacchi, Alessia, Pelagatti, Paolo (2016)
Organometallic chemistry meets crystal engineering to give responsive crystalline materials.
https://air.unipr.it/handle/11381/2806069
Chierotti, Michele R , Roberto, Gobetto, Carlo, Nervi, Bacchi, Alessia, Pelagatti, Paolo, Valentina, Colombo, Angelo, Sironi (2014)
Probing Hydrogen Bond Networks in Half-Sandwich Ru(II) Building Blocks by a Combined1H DQ CRAMPS Solid-State NMR, XRPD, and DFT Approach.
https://air.unipr.it/handle/11381/2670065
A Bacchi, A Brillante, D Crocco, M R Chierotti, R G Della Valle, A Girlando, M Masino, P Pelagatti, E Venuti (2014)
Exploration of the polymorph landscape for 1,1,4,4-tetraphenyl-1,3-butadiene.
https://air.unipr.it/handle/11381/2761702
Bacchi, Alessia, Cantoni, Giulia, Crocco, Domenico, Granelli, M , Pagano, P , Pelagatti, Paolo (2014)
Hydrogen-bond networks in polymorphs and solvates of metallorganic complexes containing ruthenium and aminoamide ligands.
https://air.unipr.it/handle/11381/2670066
Giuseppe M Lombardo, Antonio Rescifina, Ugo Chiacchio, Alessia Bacchi, Francesco Punzo (2014)
A top–down approach to crystal engineering of a racemic Δ2-isoxazoline.
https://air.unipr.it/handle/11381/2761703
Bacchi, Alessia, Cantoni, Giulia, Pelagatti, Paolo (2013)
Polymorphs and co-crystal with half-sandwich Ru(ii) dimers [(η6-arene)RuX2]2.
https://air.unipr.it/handle/11381/2682095
Bacchi, Alessia, G , Cantoni, Mezzadri, Francesco, Pelagatti, Paolo (2012)
From Local Control to Collective Response: Fabrication ofResponsive Organometallic Crystalline Materials by Careful Design ofFunctionalities and Tailoring of the Intermolecular Interactions.
https://air.unipr.it/handle/11381/2450836
Balestri, Davide, Bassanetti, Irene, Canossa, Stefano, Gazzurelli, Cristina, Bacchi, Alessia, Bracco, Silvia, Comotti, Angiolina, Pelagatti, Paolo (2018)
Changing the Dress to a MOF through Fluorination and Transmetalation. Structural and Gas-Sorption Effects.
https://air.unipr.it/handle/11381/2850963
Capucci, Davide, Balestri, Davide, Mazzeo, PAOLO PIO, Pelagatti, Paolo, Rubini, K , Bacchi, Alessia (2017)
Liquid Nicotine Tamed in Solid Forms by Cocrystallization.
https://air.unipr.it/handle/11381/2830678
Alessia Bacchi, *, Davide Capucci, †, Marco Giannetto, †, Monica Mattarozzi, †, Paolo Pelagatti, †, Nair Rodriguez-Hornedo, †, Katia Rubini, ‡, Andrea, Sala (2016)
Turning Liquid Propofol into Solid (without Freezing It): Thermodynamic Characterization of Pharmaceutical Cocrystals Built with a Liquid Drug.
https://air.unipr.it/handle/11381/2817274
Bacchi, Alessia, Pelagatti, Paolo (2016)
Organometallic chemistry meets crystal engineering to give responsive crystalline materials.
https://air.unipr.it/handle/11381/2806069
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